First of all, you need to make sure your computer is running Windows Pro edition, If it is Home edition, then you won't be able to add a work account.
If you have Pro, to do so, go to Settings > Accounts > Access Work or School, click on Connect.
Don't sign into your work email yet. Instead, click on "Join this device to Microsoft Entra ID". On the next step, you will be prompted to sign in, then you can sign in.
Once done, restart the computer and you can use "switch user" to sign in using the company email.
===============
However, since you are solopreneur, I strongly recommend against using your work account for Windows log in. This is more for larger organizations who have dedicated IT department, so it allows IT to manage devices via Microsoft's admin center/device management, etc. As solopreneur, by doing it this way you are making it a lot more complicated to manage your computer. I suggest you set it up with your personal account for Windows login. You can still use your Microsoft 365 apps logging in with your business account.