It depends on exactly what kind of key it is. If the key was originally for Windows 10 and you upgraded to Windows 11 through the free upgrade offer, the activation is normally tied to the digital license of your device rather than a specific key. That means Windows 11 should automatically reactivate once it detects the hardware and recognizes the digital license online.
If the 25-digit key you found is the original Windows 10 key, you can try entering it in the activation settings of Windows 11. Sometimes it will work to activate, especially if the key was linked to that device. If Windows doesn’t accept it, you may need to use the "Troubleshoot" option in the activation settings. This can often detect the digital license and reactivate Windows without needing the key.
If you still can’t activate, you may need to contact Microsoft support. They can verify your upgrade and help reapply the digital license to your system. Make sure to have any proof of the upgrade or original Windows installation handy when doing so.
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hth
Marcin